Pretty much exactly what the title says. This is a video showing Lunamaria gaining 68 levels in a single battle (going from level 16 to level 84). I'm pretty sure this is the maximum level gain possible in a single battle, but I'd love to be proven wrong.
(And yes, I did almost complete an entire playthrough just for this demonstration. Dedication!)
Here's the setup:
Lunamaria's ace bonus: +50% experience gained
Tessa's ace bonus: +20% experience gained for those in command range
Iron Emblem: +100% experience gained
Gain: +100% experience gained
With Second Attack and enough skill to double attack Emperor of Darkness, the only thing left is to lure a Mechanical Beast beside him to make use of Support Defend. This allows you to kill two enemies in a single battle. You could probably also do this with Support Attack, but this is a simpler method.
Note that Lunamaria is at base level (16), but with partial experience toward the next level. If you try this from base level only, you'll gain 67 levels and be 168 experience short of 68. Coincidentally, this video shows a Lunamaria with 68 experience to the next level. :)
If you're wondering why I chose these enemies, it's because they appear to be the highest level enemies available that also have a Support Defend available. While the final boss is level 70, she doesn't have Support Defend. You'd only be able to kill one enemy, and being five levels higher than Emperor of Darkness doesn't even it out.
Also, if you're REALLY curious, Emperor of Darkness appears to be worth slightly more experience than Black Noir even though they are both level 65.
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