Sorry this one's so long. But Slater's rules aren't the easiest things in the world.
Summary:
For an "s" or "p" electron:
Add up 0.35 for each electron in same group;
plus 0.85 for each electron in the shell below
plus 1.00 for each electron two or more shells lower
Then subtract this sum from the atomic number to get Z(eff)
For a "d" or "f" electron:
Add up 0.35 for each electron in the same group
plus 1.00 for every electron in any other lower group
Then subtract this sum from the atomic number to get Z(eff)
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Негізгі бет Using Slater's Rules: 3 Examples
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